tburger: unpersonalized, 2 years valid prepaid debit VISA for one-time EUR 3 :-)
Plastic or virtual?
Can you upload it after use and if so what fees are applied?
The best virtual prepaid credit card I found so far for Germans (as in least fees and risk) is
Wirecard's virtual MasterCard.
Back on the topic:
The main problem I see is in supporting a multitude of payment possibilities, which takes quite some work up front to design (want to be secure as well!) and still a little later on periodically to keep them updated. If you 'only' decide to use credit cards through PayPal (which is what GOG currently does), you cover a lot of customers with very little effort.
For a small company like GOG manpower isn't as easily wasted as with Steam.