Gundato: Depends on the person, but I think I have proved that it isn't as cut and dry as most of us would say.
captfitz: nothing in the world is cut and dry
i know that there are advantages to steam that sometimes cross over into GOG's catalogue, but there are only four or five cases of that and it's still up for debate whether they even outweigh GOG's advantages
(GOG gets an almost unfair win in a lot of ways because of how old 90% of its games are--multiplayer is inconsequential and files are small and no more new patches are realistically going to be released so automatic patching is a nonissue)
because it's so overwhelmingly in GOG's favor, it's safe to generalize--anything else is nitpicking
and let's recall: i don't really think they should be compared at all.
Agree on the comparison, but people do it.
And I wouldn't say it is as overwhelmingly in GoG's favor as you claim.
GoG has extras. Honestly, most people don't care. I know I generally only grab manuals and soundtracks (if I like the soundtrack). Nice touch, but not a dealbreaker.
And, as you mention, most of the games are older. But that actually gives Steam an advantage (assuming the game works). The Steam Overlay. XFire doesn't support something like 75% of the games here (I pulled that out of my butt, but it is probably right :p). I think every Steam game has overlay support (well, except for R6:Vegas 1). So if you don't like to alt-tab out, you can still easily chat with friends and check for solutions/tips for the more fiendish puzzles, right form ingame with Steam.
Like I said, it is going to depend on the individual. So generalization just isn't really an option.