cmdr_flashheart: Well, some words are very specific, and others can change meaning depending on the context, so I don't think there are many "unnecessarily complicated" words.
For example, defenestration, in the context you're using it, describes a specific act, and perhaps you wouldn't add this word in your normal day vocabulary, but it could be useful for literature, academics etc.
If you do not enjoy language, why do you post here anyhow?
This I think is a pleasure thread, not a frumpy one.
Defenestration, I do not it should exist without the specific ref to Prague - so to my mind it is not a literal meaning, but rather one referring to throwing out usurping powers.
"Usurping" - what say you?
Edit: grammar.